Preparation of Advanced CuO Nanowires/Functionalized Graphene Composite Anode Material for Lithium Ion Batteries

نویسندگان

  • Jin Zhang
  • Beibei Wang
  • Jiachen Zhou
  • Ruoyu Xia
  • Yingli Chu
  • Jia Huang
چکیده

The copper oxide (CuO) nanowires/functionalized graphene (f-graphene) composite material was successfully composed by a one-pot synthesis method. The f-graphene synthesized through the Birch reduction chemistry method was modified with functional group "-(CH₂)₅COOH", and the CuO nanowires (NWs) were well dispersed in the f-graphene sheets. When used as anode materials in lithium-ion batteries, the composite exhibited good cyclic stability and decent specific capacity of 677 mA·h·g-1 after 50 cycles. CuO NWs can enhance the lithium-ion storage of the composites while the f-graphene effectively resists the volume expansion of the CuO NWs during the galvanostatic charge/discharge cyclic process, and provide a conductive paths for charge transportation. The good electrochemical performance of the synthesized CuO/f-graphene composite suggests great potential of the composite materials for lithium-ion batteries anodes.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Environmental-Friendly and Facile Synthesis of Co3O4 Nanowires and Their Promising Application with Graphene in Lithium-Ion Batteries

In this work, we developed an eco-friendly strategy for preparing Co3O4 nanowires. The process consisted of two steps: controllable synthesis of metal cobalt nanowires followed by a facile air-oxidization step. The 1D nanowire structure with a high aspect ratio was easily achieved via a magnetic-field-assisted self-assembly of cobalt ion complexes during reduction. After air-calcinations, the C...

متن کامل

In-situ One-step Hydrothermal Synthesis of a Lead Germanate-Graphene Composite as a Novel Anode Material for Lithium-Ion Batteries

Lead germanate-graphene nanosheets (PbGeO3-GNS) composites have been prepared by an efficient one-step, in-situ hydrothermal method and were used as anode materials for Li-ion batteries (LIBs). The PbGeO3 nanowires, around 100-200 nm in diameter, are highly encapsulated in a graphene matrix. The lithiation and de-lithiation reaction mechanisms of the PbGeO3 anode during the charge-discharge pro...

متن کامل

SnO2 Nanowires on Carbon Nanotube Film as a High Performance Anode Material for Flexible Li-ion Batteries

Today, Li-ion batteries (LIBs) are the most common rechargeable batteries used in electronic devices. SnO2 with theoretical specific capacity of 782 mAh/g is among the best anode materials for LIBs. In this report, Three-dimensional SnO2 nanowires (NWs) on carbon nanotube (CNT) thin film (SnO2 / CNT) is fabricated using a combination of vacuum filtration and thermal evaporation techniques. The ...

متن کامل

CuGeO₃ nanowires covered with graphene as anode materials of lithium ion batteries with enhanced reversible capacity and cyclic performance.

A facile one-step route was developed to synthesize crystalline CuGeO₃ nanowire/graphene composites (CGCs). Crystalline CuGeO₃ nanowires were tightly covered and anchored by graphene sheets, forming a layered structure. Subsequently, CGCs were exploited as electrode materials for lithium ion batteries (LIBs). The reversible formation of Li₂O buffer layer and elastic graphene sheets accommodated...

متن کامل

Nitrogen-doped porous carbon nanosheets as low-cost, high-performance anode material for sodium-ion batteries.

Between the sheets: Sodium-ion batteries are an attractive, low-cost alternative to lithium-ion batteries. Nitrogen-doped porous carbon sheets are prepared by chemical activation of polypyrrole-functionalized graphene sheets. When using the sheets as anode material in sodium-ion batteries, their unique compositional and structural features result in high reversible capacity, good cycling stabil...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 10  شماره 

صفحات  -

تاریخ انتشار 2017